Volume 43 Issue 2
Sep 2022
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YU Zhihui, LIU Dandan, KOU Yanna. Preparation and Pproperties of Si/Si-Fe Alloy Porous Composite as Anode Material in Lithium-ion Battery[J]. JOURNAL OF MECHANICAL ENGINEERING, 2017, 43(2): 278-284. doi: 10.11936/bjutxb2016010005
Citation: YU Zhihui, LIU Dandan, KOU Yanna. Preparation and Pproperties of Si/Si-Fe Alloy Porous Composite as Anode Material in Lithium-ion Battery[J]. JOURNAL OF MECHANICAL ENGINEERING, 2017, 43(2): 278-284. doi: 10.11936/bjutxb2016010005

Preparation and Pproperties of Si/Si-Fe Alloy Porous Composite as Anode Material in Lithium-ion Battery

doi: 10.11936/bjutxb2016010005
  • Received Date: 05 Jan 2016
    Available Online: 13 Sep 2022
  • Issue Publish Date: 01 Feb 2017
  • In order to modify the electrochemical properties of Si anode for lithium ion batteries, a series of porous Si/Si-Fe alloy composites with different amounts of Fe doping were prepared by magnesium reduction process. The morphology and microstructure of the as-prepared composites were investigated. The electrochemical performance of the composites as anode materials for lithium-ion batteries were evaluated by galvanostatical charge-discharge testing.The composites show a porous structure with the uniform distribution of Si-Fe alloy inside the pores and possess remarkable cycle stability with a capacity of 1133.5mA·h/g at 0.1C after 100 cycles, a capacity retention ratio of 66% and a reversible capacity of 776.9mA·h/g at 1C.

     

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  • [1]
    QI P, ZHU D, CHEN Y G.Electrochemical performances of Si/graphite/carbon composites as anode materials for lithium-ion batteries[J]. Journal of Functional Materials, 2012, 43(5): 657-659. (in Chinese)
    [2]
    AUGUSTYN V, SIMON P, DUNN B.Pseudocapacitive oxide materials for high-rate electrochemical energy storage[J]. Energy & Environmental Science, 2014, 7(5): 1597.
    [3]
    GWON H, HONG J, KIM H, et al.Recent progress on flexible lithium rechargeable batteries[J]. Energy & Environmental Science, 2014, 7(2): 538.
    [4]
    GORIPARTI S, MIELE E, DE ANGELIS F, et al.Review on recent progress of nanostructured anode materials for Li-ion batteries[J]. Journal of Power Sources, 2014, 257: 421-433.
    [5]
    LI M, HOU X H, WANG J, et al.Fabrication and electrochemical performance of core-shell silicon graphite composite anode material based on graphite matrix[J]. Journal of Functional Materials, 2013, 44(19): 2828-2832. (in Chinese)
    [6]
    TERRANOVA M L, ORLANDUCCI S, TAMBURRI E, et al.Si/C hybrid nanostructures for Li-ion anodes: an overview[J]. Journal of Power Sources, 2014, 246: 167-77.
    [7]
    ZHANG L, JIANG X Y, ZHANG R.Research of Si anode for lithium-ion batteries prepared by mechanical alloying method[J]. Journal of Functional Materials, 2012, 43(19): 2638-2646. (in Chinese)
    [8]
    THABETHE S, LINGANISO E, MOTAUNG D, et al.Visible and IR photoluminescence of c-FeSi@a-Si core-shell nano-fibres produced by vapour transport[J]. Journal of Luminescence, 2013, 143: 113-119.
    [9]
    LI Z, MO L, KATHIRASER Y, et al.Yolk-Satellite-Shell structured Ni-Yolk@Ni@SiO2 nanocomposite: superb catalyst toward methane CO2 reforming reaction[J]. ACS Catalysis, 2014, 4(5): 1526-1536.
    [10]
    PARK M S, RAJENDRAN S, KANG Y M, et al.Si-Ni alloy-graphite composite synthesized by arc-melting and high-energy mechanical milling for use as an anode in lithium-ion batteries[J]. Journal of Power Sources, 2006, 158(1): 650-653.
    [11]
    SUN L, WANG X, SUSANTYOKO R A, et al.Copper-silicon core-shell nanotube arrays for free-standing lithium ion battery anodes[J]. Journal of Materials Chemistry A, 2014, 2(37): 15294.
    [12]
    MURUGESAN S, HARRIS J T, KORGEL B A, et al.Copper-coated amorphous silicon particles as an anode material for lithium-ion batteries[J]. Chemistry of Materials, 2012, 24(7): 1306-1315.
    [13]
    CHEN Y, QIAN J, CAO Y, et al.Green synthesis and stable Li-storage performance of FeSi2/Si@C nanocomposite for lithium-ion batteries[J]. ACS Applied Materials & Interfaces, 2012, 4(7): 3753-3758.
    [14]
    LEE K M, LEE Y S, KIM Y W, et al.Electrochemical characterization of Ti-Si and Ti-Si-Al alloy anodes for Li-ion batteries produced by mechanical ball milling[J]. Journal of Alloys and Compounds, 2009, 472(1/2): 461-465.
    [15]
    GUO S, LI H, BAI H, et al.Ti/Si/Ti sandwich-like thin film as the anode of lithium-ion batteries[J]. Journal of Power Sources, 2014, 248: 1141-1148.
    [16]
    DU F H, LI B, FU W, et al.Surface binding of polypyrrole on porous silicon hollow nanospheres for Li-ion battery anodes with high structure stability[J]. Advanced Materials, 2014, 26(35): 6145-6150.
    [17]
    JO M R, HEO Y U, LEE Y C, et al.A nano-Si/FeSi2Ti hetero-structure with structural stability for highly reversible lithium storage[J]. Nanoscale, 2014, 6(2): 1005-1010.
    [18]
    CHEN Y, QIAN J, CAO Y, et al.Green synthesis and stable li-storage performance of FeSi(2)/Si@C nanocomposite for lithium-ion batteries[J]. ACS Applied Materials & Interfaces, 2012, 4(7): 3753-3758.
    [19]
    LI W, TANG Y, KANG W, et al.Core-shell Si/C nanospheres embedded in bubble sheet-like carbon film with enhanced performance as lithium ion battery anodes[J]. Small, 2015, 11(11): 1345-1351.
    [20]
    PARK H, LEE S, YOO S, et al.Control of interfacial layers for high-performance porous Si lithium-ion battery anode[J]. ACS Applied Materials & Interfaces, 2014, 6(18): 16360-16367.
    [21]
    HAN H K, LOKA C, YANG Y M, et al.High capacity retention Si/silicide nanocomposite anode materials fabricated by high-energy mechanical milling for lithium-ion rechargeable batteries[J]. Journal of Power Sources, 2015, 281: 293-300.
    [22]
    GE M, RONG J, FANG X, et al.Porous doped silicon nanowires for lithium ion battery anode with long cycle life[J]. Nano Letters, 2012, 12(5): 2318-2323.
    [23]
    CHAN C K, PENG H, LIU G, et al.High-performance lithium battery anodes using silicon nanowires[J]. Nature Nanotechnology, 2008, 3(1): 31-35.
    [24]
    ZHANG C L, YE X H, REN C Y, et al.The study of fluoroethylene carbonate as an additive of electrolyte solution[J]. Guangzhou Chemical Industry, 2013, 41(8): 91-93. (in Chinese)
    [25]
    LI C, ZHANG P, JIANG Z.Effect of nano Cu coating on porous Si prepared by acid etching Al-Si alloy powder[J]. Electrochimica Acta, 2015, 161: 408-412.
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