Issue 2
Feb 2016
Turn off MathJax
Article Contents
HONG Xin, TANG Ke. Adsorptive denitrification of NaY molecular sieve modified by Cr3+[J]. JOURNAL OF MECHANICAL ENGINEERING, 2016, 44(2): 251-256.
Citation: HONG Xin, TANG Ke. Adsorptive denitrification of NaY molecular sieve modified by Cr3+[J]. JOURNAL OF MECHANICAL ENGINEERING, 2016, 44(2): 251-256.

Adsorptive denitrification of NaY molecular sieve modified by Cr3+

More Information
  • Corresponding author: Tel: 86-416-4198019, E-mail: tangke0001@163.com
  • Received Date: 28 Jul 2015
  • Rev Recd Date: 10 Oct 2015
  • The modification of NaY by chromium ion was systemically studied.The modified CrY molecular sieve was characterized by X-ray diffraction (XRD), Fourier transform infrared spectrum (FT-IR) and nitrogen adsorption.The experimental results show that the optimum condition of modification are two times modification with 0.5 mol/L Cr3+at 40℃.The result of FT-IR suggested the peak disappeared at 1 147 cm-1 and the peak generated a blue shift at 1 024 cm-1, indicating that Cr3+ had exchanged Na+ in the framework of NaY molecular sieve.Static adsorption denitrification of a model fuel on CrY molecular sieve had carried out at different adsorption time and temperature.The results showed that the adsorption of quinoline on CrY molecular sieve was chemical adsorption and the adsorption type was coordination adsorption and π complex adsorption.The adsorption effect was better at room temperature for 30 min.The adsorption of quinoline over CrY molecular sieve belongs to Langmuir adsorption and Freundlich adsorption model.

     

  • loading
  • [1]
    DHEER S, ANJU C, MITRA B P, AMARJIT S S.A comparative evaluation of nitrogen compounds in petroleum distillates[J].Chromatographia, 2011, 74(1/2):121-126.
    [2]
    吕志凤, 战风涛, 李林, 苏贻勋.催化裂化柴油中氮化物的分析[J].石油化工, 2001, 30(5):399-401. http://www.cnki.com.cn/Article/CJFDTOTAL-SYHG200105014.htm

    LV Zhi-feng, ZHAN Feng-tao, LI Lin, SU Yi-xun.Separation and identification of nitrogen compounds in diesels[J].Petrochem Technol, 2001, 30(5):399-401. http://www.cnki.com.cn/Article/CJFDTOTAL-SYHG200105014.htm
    [3]
    BELTRAMONE A R, CROSSLEY S, RESASCO D E, ALVAREZ W E, CHOUDHARY T V.Inhibition of the hydrogenation and hydrodesulfurization reactions by nitrogen compounds over NiMo/Al2O3[J].Catal Lett, 2008, 123(1/2):181-185.
    [4]
    LIU K, FLORA T T.Effect of the nitrogen heterocyclic compounds on hydrodesulfurization using in situ hydrogen and a dispersed Mo catalysi[J].Catal Today, 2010, 149(1/2):28-34.
    [5]
    HANAFL S A, MOHAMED M S.Recent trends in the cleaning of diesel fuels via desulfurization processes[J].Energy Source Part A, 2011, 33(6):495-511. doi: 10.1080/15567030903058360
    [6]
    SANO Y, CHOI K H, KORAI Y.Effects of nitrogen and refractory sulfur species removal on the deep HDS of gas oil[J].Appl Catal B:Environ, 2004, 53(3):169-174. doi: 10.1016/j.apcatb.2004.05.014
    [7]
    RABARIHOELA-RAKOTOVAO V, DIEHL F, BRUNET S.Compounds on the transformation of the refractory 4, 6-Dimethyldibenzothiophene over a NiMoP/Al2O3 catalyst[J].Catal Lett, 2009, 129:50-60. doi: 10.1007/s10562-008-9777-x
    [8]
    JVRGEN B, JVRGEN K.Andreas Weigel Olaf Schröder, Thomas Brüning, Michael Müller Ernst Hallier, G tz Westphal.Influence of fuel properties, nitrogen oxides, and exhaust treatment by an oxidation catalytic converter on the mutagenicity of diesel engine emissions[J].Arch Toxicol, 2006, 80(8):540-546. doi: 10.1007/s00204-006-0088-y
    [9]
    刘兴利, 王榕, 李永红.吸附法脱除烷基化用汽油中的碱性氮化物[J].离子交换与吸附, 2009, 25(1):45-51. http://www.cnki.com.cn/Article/CJFDTOTAL-LJYX200901008.htm

    LIU Xing-li, WANG Rong, LI Yong-hong.Denitrogenation of FCC denitrogenation of FCC gasoline used as the feedstock of alkylation by several different adsorbents[J].Ion Exc Adsorpt, 2009, 25(1):45-51. http://www.cnki.com.cn/Article/CJFDTOTAL-LJYX200901008.htm
    [10]
    陈月株, 孙玉华, 周亚松.石油馏分中脱除氮化物的方法:中国, CN 1045459C[P].1999-10-06.

    CHEN Yue-zhu, SUN Yu-hua, ZHOU Ya-song.Method of removing nitrogen compounds in petroleum fractions:CN, CN 1045459C[P].1999-10-06.
    [11]
    朱金柱, 沈健.SBA-15吸附脱除油品中的碱性氮化物[J].石油学报 (石油加工), 2012, 40(11):566-570.

    ZHU Jin-zhu, SHEN Jian.Adsorption of basic nitrogen compounds from oil by SBA-15 zeolite[J].Acta Pet Sin (Pet Process Sect), 2012, 40(11):566-570.
    [12]
    LAREDO G C, VEGA-MERINO P M, TREJO-ZÁRRAGA F, CASTILLO J.Denitrogenation of middle distillates using adsorbent materials towards ULSD production:A review[J].Fuel Process Technol, 2013, 106:21-32. doi: 10.1016/j.fuproc.2012.09.057
    [13]
    徐晓宇, 孙悦, 沈健, 翟玉龙.HY和USY分子筛对模拟油品中碱性氮化物的吸附行为[J].化工进展, 2014, 33(4):1035-1040. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201404052.htm

    XU Xiao-yu, SUN Yue, SHEN Jian, ZHAI Yu-long.Adsorption behavior of basic nitrides in model oil on HY and USY molecular sieves[J].Chem Ind Eng Prog, 2014, 33(4):1035-1040. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201404052.htm
    [14]
    翟玉龙, 沈健.HY分子筛吸附脱除油品中碱性氮化物的研究[J].石油炼制与化工, 2011, 42(1):41-44. http://www.cnki.com.cn/Article/CJFDTOTAL-SYLH201101017.htm

    ZHAI Yu-long, SHEN Jian.Study on the adsorption of basic nitrogen compounds from oil with HY molecular sieve[J].Pet Process Petrochem, 2011, 42(1):41-44. http://www.cnki.com.cn/Article/CJFDTOTAL-SYLH201101017.htm
    [15]
    王福帅, 李会鹏, 赵华, 房斌斌.NaY/β复合分子筛改性及对模拟柴油中氮化物的吸附性能[J].石油炼制与化工, 2012, 43(11):59-62. http://www.cnki.com.cn/Article/CJFDTOTAL-SYLH201211016.htm

    WANG Fu-shuai, LI Hui-peng, ZHAO Hua, FANG Bin-bin.Modification of NaY/β composite molecular sieve and its adsorption performance of removing nitrogen containing compounds in model oil[J].Pet Process Petrochem, 2012, 43(11):59-62. http://www.cnki.com.cn/Article/CJFDTOTAL-SYLH201211016.htm
    [16]
    唐磊, 沈健.改性Y型分子筛吸附脱除油品中碱性氮化物的研究[J].应用化工, 2014, 43(6):1078-1085. http://www.cnki.com.cn/Article/CJFDTOTAL-SXHG201406030.htm

    TANG Lei, SHEN Jian.Study on adsorpting basic nitrogen compounds from oil with the modified Y zeolite[J].Appl Chem Ind, 2014, 43(6):1078-1085. http://www.cnki.com.cn/Article/CJFDTOTAL-SXHG201406030.htm
    [17]
    洪新, 唐克.NaY分子筛的改性及吸附脱氮性能[J].燃料化学学报, 2015, 43(2):214-220. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18577.shtml

    HONG Xin, TANG Ke.Modification and adsorptive denitrification of NaY molecular sieve[J].J Fuel Chem Technol, 2015, 43(2):214-220. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18577.shtml
    [18]
    ZHANG H, SONG H Y.Study of adsorptive denitrogenation of diesel fuel over mesoporous molecular sieves based on breakthrough curves[J].Ind Eng Chem Res, 2012, 51:16059-16065. doi: 10.1021/ie302169r
    [19]
    迟志明.介孔分子筛用于柴油吸附脱氮的基础研究[D].北京:中国石油大学, 2010.

    CHI Zhi-ming.Basic research of Al-MCM-41 molecular sieve for denitrogenation of diese oil[D].Beijing:China University of Petroleum, 2010.
    [20]
    张晗.燃料中含氮化合物的吸附脱除[D].大连:大连理工大学, 2009.

    ZHANG Han.Adsorptive removal of nitrogen-containing compounds from fuel[D].Dalian:Dalian University of Technology, 2009.
    [21]
    洪新, 唐克.杂原子介孔Co-MCM-41分子筛的制备及其吸附脱氮性能[J].燃料化学学报, 2015, 43(6):720-727. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18646.shtml

    HONG Xin, TANG Ke.Preparation and deep adsorption denitrification from diesel oil of heteroatoms mesoporous molecular sieve Co-MCM-41[J].J Fuel Chem Technol, 2015, 43(6):720-727. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18646.shtml
    [22]
    罗勤慧, 沈孟长, 丁益.Cr3+的水解聚合作用的研究[J].化学学报, 1982, 40(2):125-132.

    LUO Qin-hui, SHEN Meng-chang, DING Yi.Studies on the hydrolytic polymerization of Cr3+ Ⅰ[J].Acta Chim Sin, 1982, 40(2):125-132.
  • 加载中

Catalog

    Figures(9)

    Article Metrics

    Article views(182) PDF downloads(0) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return