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处置库膨润土胶体吸附迁移性及核素共同迁移特性研究进展

陈永贵 蔡叶青 叶为民 崔玉军 陈宝

陈永贵, 蔡叶青, 叶为民, 崔玉军, 陈宝. 处置库膨润土胶体吸附迁移性及核素共同迁移特性研究进展[J]. 机械工程学报, 2021, 43(12): 2149-2158. doi: 10.11779/CJGE202112001
引用本文: 陈永贵, 蔡叶青, 叶为民, 崔玉军, 陈宝. 处置库膨润土胶体吸附迁移性及核素共同迁移特性研究进展[J]. 机械工程学报, 2021, 43(12): 2149-2158. doi: 10.11779/CJGE202112001
CHEN Yong-gui, CAI Ye-qing, YE Wei-min, CUI Yu-jun, CHEN Bao. Progresses in researches on adsorption and migration properties of bentonite colloids and their co-migration with nuclide in repository[J]. JOURNAL OF MECHANICAL ENGINEERING, 2021, 43(12): 2149-2158. doi: 10.11779/CJGE202112001
Citation: CHEN Yong-gui, CAI Ye-qing, YE Wei-min, CUI Yu-jun, CHEN Bao. Progresses in researches on adsorption and migration properties of bentonite colloids and their co-migration with nuclide in repository[J]. JOURNAL OF MECHANICAL ENGINEERING, 2021, 43(12): 2149-2158. doi: 10.11779/CJGE202112001

处置库膨润土胶体吸附迁移性及核素共同迁移特性研究进展

doi: 10.11779/CJGE202112001
基金项目: 

国家自然科学基金项目 41977232

国家自然科学基金项目 41772279

国家自然科学基金项目 42030714

详细信息
    作者简介:

    陈永贵(1976— ),男,安徽宿松人,教授,博士生导师,主要从事环境地质和非饱和土力学方面的研究。E-mail:cyg@tongji.edu.cn

  • 中图分类号: TU41

Progresses in researches on adsorption and migration properties of bentonite colloids and their co-migration with nuclide in repository

  • 摘要: 在阐述高放射性废物深地质处置库内膨润土胶体吸附迁移特性的基础上,总结了胶体与核素的共迁移试验、作用机理和模拟等方面研究成果。结果表明,膨润土胶体的吸附、迁移性受胶体浓度、地下水离子强度和pH影响显著,已有成果难以评价膨润土胶体对核素的吸附能力以及胶体的迁移能力。实验室动态柱试验和原位偶极子流场试验都关注到可移动胶体对核素迁移的促进作用以及过滤胶体对核素迁移的阻滞作用,但缺乏原位远距离胶体和核素共迁移试验成果。膨润土胶体和核素共迁移效果受胶体的吸附-解吸和胶体过滤作用控制,鲜少考虑介质的阻塞作用。双重渗透率模型和双重孔隙介质模型能够模拟特定条件下膨润土胶体和核素的共迁移穿透曲线,但考虑的裂隙系统简单,未考虑核素的竞争吸附效应。最后,提出了试验和理论方面的研究建议。

     

  • 图  膨润土胶体形成及核素迁移[9]

    Figure  1.  Colloid formation and radionuclide migration [9]

    图  不同因素影响下的胶体吸附性

    Figure  2.  Adsorption properties of bentonite colloids under different influences

    图  膨润土胶体的快速迁移特征[21]

    Figure  3.  Rapid migration characteristics of bentonite colloids [21]

    图  不同因素影响下的胶体迁移性[17, 25]

    Figure  4.  Migration properties of bentonite colloids under different influences [17, 25]

    图  柱试验装置示意图[17, 27-28]

    Figure  5.  Schematic diagram of column test devices [17, 27-28]

    图  动态柱胶体-核素共迁移试验结果

    Figure  6.  Results of dynamic column co-migration tests

    图  偶极子流场试验原理

    Figure  7.  Schematic diagram of dipole flow field tests

    图  原位偶极子流场共迁移试验结果[34]

    Figure  8.  Results of dipole flow field migration [34]

    图  胶体-核素共迁移作用机理[22, 35]

    Figure  9.  Mechanism of colloid and nuclide co-migration[22, 35]

    图  10  核素在膨润土胶体的吸附-解吸动力学[37]

    Figure  10.  Adsorption-desorption kinetics of bentonite colloids [37]

    图  11  双重渗透率模型模拟结果[27]

    Figure  11.  Simulated results of dual permeability model[27]

    图  12  双重孔隙介质模型模拟结果[48]

    Figure  12.  Simulated results of double-porosity model [48]

    表  1  离子强度和pH对共迁移影响

    Table  1.   Effect of ionic strength and pH on co-migration

    核素-胶体电解质(Ⅰ; pH)胶体状态穿/%效果文献
    Cs(Ⅰ)DW稳定、可移动0.08促进文献[29]
    Cs+BC 1.89
    Sr(Ⅱ)NaClO4 50 mM; 9.5稳定、可移动72促进文献[21]
    Sr+BC  100
    U(Ⅵ)NaCl 1 mM; 7稳定、可移动45促进文献[16]
    U+BC  68
    Cs(Ⅰ)碳酸盐微咸水170 mM; 7.6不稳定0.03~0.29促进文献[30]
    Cs+BC0.27~0.31
    Ce(Ⅲ)17~41阻滞
    Ce+BC0.8~1.4
    U(Ⅵ)39~67阻滞
    U+BC23~40
    Eu(Ⅲ)NaCl 1 mM; 6.5稳定、可移动34促进文献[17]
    Eu+BC  78
    Eu(Ⅲ)NaCl 10 mM; 6.5不稳定68阻滞
    Eu+BC  18
    Eu(Ⅲ)NaCl 1 mM; 3.5不稳定58阻滞
    Eu+BC  39
    下载: 导出CSV

    表  2  偶极子流场胶体-核素共迁移结果[34]

    Table  2.   Co-migration results in dipole flow field [34]

    试验内容胶体分数/%阻滞因子回收率/%
    1单独迁移I(Ⅰ)-13101100
    Sr(Ⅱ)-850387
    Am(Ⅲ)-2436~580.8830
    Pu(Ⅳ)-2425~580.8718
    Th(IV)-23220~300.86
    Np(Ⅴ)-2370~10197
    U(Ⅵ)-2380~12153
    2共迁移I(Ⅰ)-131+BC0192
    Sr(II)-85+BC02.588
    Am(Ⅲ)-241+BC990.955
    Pu(IV)-244+BC840.977
    Th(IV)-232 + BC940.955
    Np(Ⅴ)-237 + BC0~1178
    U(Ⅵ)-233 + BC6198
    Cs-137+BC80.81;12170
    下载: 导出CSV
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  • 收稿日期:  2021-03-23
  • 网络出版日期:  2022-12-02
  • 刊出日期:  2021-12-01

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