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含钨难熔高熵合金的制备、结构与性能

黄文军 乔珺威 陈顺华 王雪姣 吴玉程

黄文军, 乔珺威, 陈顺华, 王雪姣, 吴玉程. 含钨难熔高熵合金的制备、结构与性能[J]. 机械工程学报, 2021, 70(10): 106201. doi: 10.7498/aps.70.20201986
引用本文: 黄文军, 乔珺威, 陈顺华, 王雪姣, 吴玉程. 含钨难熔高熵合金的制备、结构与性能[J]. 机械工程学报, 2021, 70(10): 106201. doi: 10.7498/aps.70.20201986
Huang Wen-Jun, Qiao Jun-Wei, Chen Shun-Hua, Wang Xue-Jiao, Wu Yu-Cheng. Preparation, structures and properties of tungsten-containing refractory high entropy alloys[J]. JOURNAL OF MECHANICAL ENGINEERING, 2021, 70(10): 106201. doi: 10.7498/aps.70.20201986
Citation: Huang Wen-Jun, Qiao Jun-Wei, Chen Shun-Hua, Wang Xue-Jiao, Wu Yu-Cheng. Preparation, structures and properties of tungsten-containing refractory high entropy alloys[J]. JOURNAL OF MECHANICAL ENGINEERING, 2021, 70(10): 106201. doi: 10.7498/aps.70.20201986

含钨难熔高熵合金的制备、结构与性能

doi: 10.7498/aps.70.20201986
详细信息
    通讯作者:

    E-mail: ycwu@hfut.edu.cn

  • 中图分类号: 62.20.fg, 66.70.Df, 71.20.Lp, 81.05.Bx

Preparation, structures and properties of tungsten-containing refractory high entropy alloys

More Information
  • 摘要: 高熵合金(high-entropy alloys, HEAs)作为一种新型多主元合金, 原子排列有序、化学无序, 具有高熵、晶格畸变、缓慢扩散、“鸡尾酒”等四大效应, 表现出优异的组合性能, 有望作为新型高温结构材料、耐磨性材料、抗辐照材料应用于航空航天、矿山机械、核聚变反应堆等领域. 本文介绍了目前含钨HEAs的发展现状、常用的制备方法、微观结构和相组成. 针对HEAs优异的综合性能, 总结了目前含钨难熔HEAs的力学性能、抗摩擦磨损、抗辐照等性能, 对含钨难熔HEAs后续的研究方向进行了展望.

     

  • 图  强度与温度的关系[41]

    Figure  1.  The relationship between strength and temperature[41].

    图  NbMoTaWHEAs薄膜的制备与表征[56]

    Figure  2.  Fabrication and characterization of NbMoTaW HEA films[56].

    图  增材制造示意图[59]

    Figure  3.  Schematic illustration of additive manufacturing[59].

    图  NbMoTaW和VNbMoTaW的SEM背散射图像[39]

    Figure  4.  SEM backscatter electron images of a polished coss-section of NbMoTaW and VNbMoTaW[39].

    图  室温工程应力应变曲线[40,51]

    Figure  5.  Compressive engineering stress-strain curves at room temperature[40,51].

    图  CuMoTaWV难熔HEAs纳米柱及其工程应力应变曲线[53]

    Figure  6.  Nanopillar of CuMoTaWV: (a, b) before and (c) after the compression test, and (d) stress-strain plot from nanocompression[53].

    图  合金屈服强度与温度的关系[40]

    Figure  7.  The temperature dependence of the yield stress of Nb25Mo25Ta25W25 and V20Nb20Mo20Ta20W20 HEAs and two superalloys, Inconel 718 and Haynes 230[40].

    图  不同的工艺参数和基底制备MoFeCrTiWAlNbHEAs涂层的结果[58]

    Figure  8.  Wear volume loss of HEA coatings fabricated by laser cladding with various processing parameters and substrate after sliding time for 15 min[58].

    图  相应图表的结构以及两种合金在每个滑动距离和所使用的计数器体的磨损率值 (a) 滑动距离400 m; (b) 滑动距离1000 m; (c) 滑动距离2000 m [99]

    Figure  9.  Comparative diagrams of the volume loss (left) and the wear rate (right) of Mo20Ta20W20Nb20V20 versus Inconel 718, tested with both an alumina and a steel ball for sliding distances of (a) 400 m, (b) 1000 m, and (c) 2000 m, respectively[99].

    图  10  在1073 K下1–MeV Kr+2原位辐照HEAs的TEM明场显微图[55]

    Figure  10.  Bright-field TEM micrographs as a function of dpa of in situ 1–MeV Kr+2-irradiated HEA at 1073 K using a dpa rate of 0.0016 dpa/s: (A) Pre-irradiation; (B) 0.2 dpa; (C) 0.6 dpa; (D) 1.0 dpa; (E) 1.6 dpa; (F) 3.2 dpa; (G) 4.8 dpa; (H) 6.4 dpa; (I) 8 dpa[55].

    图  11  合金准静态与动态下的真实应力应变曲线和在高速冲击下的侵彻性能[76]

    Figure  11.  The true compressive stress-strain curve of the alloy under quasi-static and dynamic conditions and its penetration performance under high-speed impact[76].

    图  12  (CrNbTaTiW)C薄膜和不锈钢参考材料的动电位极化曲线[80]

    Figure  12.  Potential polarization curve of (CrNbTaTiW)C film and stainless steel[80].

    表  1  近年来一些典型钨HEAs的相组成

    Table  1.   Phase composition of some typical Tungsten high entropy alloys in recent years.

    年份 合金 条件 文献
    2010 NbMoTaW AC BCC [39]
    2010 VNbMoTaW AC BCC [39]
    2012 Ti-Nb-Ta-W MS BCC [60]
    2015 CrFeNiV0.5W0.25 AC FCC+ $ \sigma $ [61]
    2015 CrFeNiV0.5W0.5 AC BCC+FCC+ $ \sigma $ [61]
    2015 CrFeNiV0.5W0.75 AC BCC+FCC+ $ \sigma $ [61]
    2015 CrFeNiV0.5W AC BCC+FCC+ $ \sigma $ [61]
    2015 CrFeNi2V0.5W0.25 AC FCC+ $ \sigma $ [61]
    2015 CrFeNi2V0.5W0.5 AC FCC+ $ \sigma $ [61]
    2015 CrFeNi2V0.5W0.75 AC BCC+FCC+ $ \sigma $ [61]
    2015 CrFeNi2V0.5W AC BCC+FCC+ $ \sigma $ [61]
    2015 Cr0.5VNbMoTaW AC BCC [62]
    2015 CrVNbMoTaW AC BCC [62]
    2015 Cr2VNbMoTaW AC BCC [62]
    2016 VZrMoTaW AC(+A) BCC+ BCC+HCP+Laves [63]
    2016 VNbTaW AC BCC [64]
    2016 TiVNbTaW AC BCC [64]
    2017 TiNbMoTaW AC BCC [65]
    2017 TiVNbMoTaW AC BCC [65]
    2017 TixNbMoTaW (x = 0–1) AC BCC [66]
    2017 TiVCrTaWx MA+SPS BCC [67]
    2018 VCrMoTaW MA BCC [68]
    2018 V11Cr15Ta36W38 MS BCC [55]
    2018 AlTiCrFeNbMoW LC BCC+IM [58]
    2018 Ti8Nb23Mo23Ta23W23 MA+SPS BCC+Carbide [51]
    2018 VCrFeTaxWx(x = 0.1, 0.2) AC BCC [69]
    2018 VCrFeTaxWx(x = 0.3) AC BCC1+BCC2 [69]
    2018 VCrFeTaxWx (x = 0.4, 1) AC BCC1+BCC2+Laves [69]
    2018 VNbMoTaW MA+HPHT BCC [50]
    2019 VCuMoTaW MA BCC [49,53]
    2019 V26.4Cr31.3Mo23.6W18.7 AC BCC [70]
    2019 TiNiNbTaW AC BCC+ $ \mu $ [71]
    2019 Al10Ti18Ni18Nb18Ta18W18 AC BCC+ $ \mu $+L21 [71]
    2019 VCrNbMoTaW MA+SPS BCC+Laves [48]
    2019 Ti34.4Nb32.9Mo17W15.7 AC BCC [72]
    2019 Mo-Ru-Rh­W-Ir AC BCC+HCP+FCC [73,74]
    2019 AlTiCrFe1.5NbxMoW (x = 1.5–3) LC BCC+MC+Laves [75]
    2019 TiCrNbMoW MA+SPS BCC+Laves [47]
    2020 FeNiMoW AC FCC+BCC+ $ \mu $ [76]
    2020 V2.5Cr1.2Co0.04MoW AC BCC [77]
    2020 NbMoReTaWTa AC+A BCC [44]
    2020 (TiNbMoW)100–xCrx (x = 5–20) MA+SPS BCC+Laves [43]
    2020 (VNbMoTaW)99B1 MA+HPHT BCC [78]
    AC = 铸造, MS = 磁控溅射, A = 热处理, MA = 球磨, SPS = 放电等离子烧结, LC = 激光熔覆, HPHT = 高压/高压固结技术
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出版历程
  • 收稿日期:  2020-11-25
  • 修回日期:  2020-12-21
  • 网络出版日期:  2021-05-27
  • 发布日期:  2021-05-27

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